Page 39 - Analysis Report of Global Market in the Submarine Cable Field (2017)
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Where, E is the young’s modulus of the silica glass, r is the surface energy   Fig.2 Tensile strength test of SeaCom ®
          of the silica glass, a is the bond length of the Si-O chemical bond, and the
          Sf is the cross-sectional area of the silica fiber. It can be calculated that
          the theoretical fracture strength of the conventional 125μm fiber is about
          15.6GPa. But in the process of preform manufacturing and melt drawing
          of glass will inevitably produce defects or cracks because of stress and
          impurity, and micro cracks will continue to growth. The fiber will break
          when the crack expands to a certain extent as shown in figure 1.
          Fig.1 Crack growth in optical fiber







                                                                 Fig.3 Tensile strength test result before and after aging
         According to the Griffith theory, the actual fracture strength of silica fiber is
         deduced:
                                                            (2)

         Where, L is the depth of micro crack, unit m. When the micro crack
         depth is 0.1nm, the fracture strength of the optical fibers is only 7.5kg,
         much lower than the theoretical strength, so the formation and growth
         of micro cracks is the important factor which leads to the fracture and
         the fatigue life decrease of optical fiber.

         In the high temperature graphite furnace, the temperature of the fiber
         is changed from the high temperature to the low temperature, the
         chemical reaction is easy to occur in the region of 2200℃, and the silicon
         monoxide vapor is produced:
                                                            (3)
         When the fiber is in the region of 1400~-1600~, the silicon monoxide   Subsequently, the Nd fatigue strength of the fiber was measured and
         vapor will continue to react with carbon:               calculated of the SeaCom® optical fiber, including initial, gel aged
                                                            (4)  and damp-heat aged fiber, as shown in figure 4. All test results are
         The silicon carbide solid particles produced in the reaction can be easily   higher than 25, which indicate that the improvement of the silica glass
         embedded into the silica glass that has not been transformed into solid   and the coating material can improve the fatigue life. This makes it
         state.                                                  possible to improve the reliability and safety of submarine optical cable,
                                                                 which is of great significance to the important and expensive Marine
         Therefore, the project has optimized the structure and temperature   Communication.
         field distribution of the drawing furnace in order to improve the tensile   Fig.4 Nd test result before and after aging
         strength and proof pass rate. In addition, the project also improved
         the purification of the gas raw material, the pre release of the internal
         stress of the preform, the concentration ratio of mixed acid, the acid
         pickling time and the component of the resin coating material. It is
         worth mentioning that the preform pickling time should be properly
         controlled, mild corrosion will not be able to effectively remove
         pollutants of the preform surface, in contrast, the severe corrosion will
         leads to micro cracks on the surface of the perform.
          High strength marine optical fiber were successfully prepared using
          the above techniques and registered as the trademark "SeaCom®".The
          tensile strength of the SeaCom® marine fiber is shown in figure 2. The
          sample is taken as an example, the fracture force is 73.79N, and the
          stress is 6012.788MPa. In the case of good fiber strength, stretch without
          skidding, the tensile curve is close to a straight line.

          The optical fiber gel aging (gel soaking, 85℃, 30d) and damp-heat
          aging (85℃, 85% RH, 30d) test were also carried out. A large number of   2.2Large Reel Length Technology
          tensile strength tests and analyses are performed on the initial fiber and   After the improvement of the optical fiber strength, it can effectively
          the aged fiber, as shown in figure 3. The results show a good distribution   reduce the fiber breakage rate under the high tension proof, reduce
          of tensile strength of initial, gel aged and damp-heat aged fiber. The   the fiber splice point, thus greatly reduce the unreliable factors in the
          median strength is more than 6.0GPa, and the Weibull slope is more than   long distance communication. Therefore, it is necessary to enlarge the
          130 with the cumulative probability 15%-85%.           traditional 25km and 50km reel length for high strength optical fiber.
                                                                 In the design of the optical fiber reel capacity, the optical fiber can be
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